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BibTeX file of [Aleksich23] [show it without abstract] @article{Aleksich23, author={Mariya Aleksich and Daniel W. Paley and Elyse A. Schriber and Will Linthicum and Vanessa Oklejas and David W. Mittan-Moreau and Ryan P. Kelly and Patience A. Kotei and Anita Ghodsi and Raymond G. Sierra and Andrew Aquila and Fr{\'e}d{\'e}ric Poitevin and Johannes P. Blaschke and Mohammad Vakili and Christopher J. Milne and Fabio Dall'Antonia and Dmitry Khakhulin and Fernando Ardana-Lamas and Frederico Lima and Joana Valerio and Huijong Han and Tamires Gallo and Hazem Yousef and Oleksii Turkot and Ivette J. Bermudez Macias and Thomas Kluyver and Philipp Schmidt and Luca Gelisio and Adam R. Round and Yifeng Jiang and Doriana Vinci and Yohei Uemura and Marco Kloos and Mark Hunter and Adrian P. Mancuso and Bryan D. Huey and Lucas R. Parent and Nicholas K. Sauter and Aaron S. Brewster and J. Nathan Hohman}, title={{XFEL} Microcrystallography of Self-Assembling Silver $n$-Alkanethiolates}, journal={J. Am. Chem. Soc.}, volume={145}, pages={17042--17055}, year={2023}, keywords={European XFEL;}, url={https://doi.org/10.1021/jacs.3c02183}, doi={10.1021/jacs.3c02183}, abstract={New synthetic hybrid materials and their increasing complexity have placed growing demands on crystal growth for single-crystal X-ray diffraction analysis. Unfortunately, not all chemical systems are conducive to the isolation of single crystals for traditional characterization. Here, small-molecule serial femtosecond crystallography (smSFX) at atomic resolution (0.833 \AA) is employed to characterize microcrystalline silver $n$-alkanethiolates with various alkyl chain lengths at X-ray free electron laser facilities, resolving long-standing controversies regarding the atomic connectivity and odd--even effects of layer stacking. smSFX provides high-quality crystal structures directly from the powder of the true unknowns, a capability that is particularly useful for systems having notoriously small or defective crystals. We present crystal structures of silver $n$-butanethiolate (C4), silver n-hexanethiolate (C6), and silver n-nonanethiolate (C9). We show that an odd--even effect originates from the orientation of the terminal methyl group and its role in packing efficiency. We also propose a secondary odd--even effect involving multiple mosaic blocks in the crystals containing even-numbered chains, identified by selected-area electron diffraction measurements. We conclude with a discussion of the merits of the synthetic preparation for the preparation of microdiffraction specimens and compare the long-range order in these crystals to that of self-assembled monolayers.} } Mariya Aleksich, Daniel W. Paley, Elyse A. Schriber, Will Linthicum, Vanessa Oklejas, David W. Mittan-Moreau, Ryan P. Kelly, Patience A. Kotei, Anita Ghodsi, Raymond G. Sierra, Andrew Aquila, Frédéric Poitevin, Johannes P. Blaschke, Mohammad Vakili, Christopher J. Milne, Fabio Dall'Antonia, Dmitry Khakhulin, Fernando Ardana-Lamas, Frederico Lima, Joana Valerio, Huijong Han, Tamires Gallo, Hazem Yousef, Oleksii Turkot, Ivette Bermudez J. Macias, Thomas Kluyver, Philipp Schmidt, Luca Gelisio, Adam R. Round, Yifeng Jiang, Doriana Vinci, Yohei Uemura, Marco Kloos, Mark Hunter, Adrian P. Mancuso, Bryan D. Huey, Lucas R. Parent, Nicholas K. Sauter, Aaron S. Brewster, and Nathan J. Hohman, XFEL Microcrystallography of Self-Assembling Silver n-Alkanethiolates, J. Am. Chem. Soc. 145, 17042–17055 (2023) ![[abstract]](/biblio/img/abstract.gif) [abstract]![[link]](/biblio/img/link.gif) doi:10.1021/jacs.3c02183
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